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Ethylene glycol diacetate;2-(Acetyloxy)ethyl acetate

Ethylene glycol diacetate Chemical Properties

Melting point -41 °C (lit.)
Boiling point 186-187 °C (lit.)
density 1.104 g/mL at 20 °C (lit.)
vapor density 5.04 (vs air)
vapor pressure 0.2 mm Hg ( 20 °C)
refractive index n20/D 1.431(lit.)
Fp 198 °F
storage temp. 2-8°C
solubility 160g/l
form Liquid
color blue
explosive limit 1.6%, 135°F
Water Solubility 160 g/L (20 ºC)
Merck 14,3799
BRN 1762308
LogP 0.1 at 40℃
CAS DataBase Reference 111-55-7(CAS DataBase Reference)
NIST Chemistry Reference 1,2-Ethanediol, diacetate(111-55-7)
EPA Substance Registry System Ethylene glycol diacetate (111-55-7)

Safety Information

Hazard Codes Xn,Xi
Risk Statements 36/37/38
Safety Statements 26-36-24/25-22
WGK Germany 1
RTECS KW4025000
F 3
Autoignition Temperature 899 °F
TSCA Yes
HS Code 29153900
Hazardous Substances Data 111-55-7(Hazardous Substances Data)
Toxicity LD50 orally in rats: 6.86 g/kg (Smyth)

Ethylene glycol diacetate Usage And Synthesis

Chemical Properties clear liquid
Uses Solvent for oils, cellulose esters, explosives, etc.
Uses EGDA imparts excellent flow properties in baking lacquers and enamels and where thermoplastic acrylic resins are used. It is also a good solvent for cellulosic coatings and can be used in some ink systems such as screen inks. It has found use as a perfume fixative, and has reported applications in waterborne adhesives.
Uses Ethylene glycol diacetate may be used as an acyl donor for the in situ generation of peracetic acid, during the chemoenzymatic synthesis of caprolactone. It may be employed as a precursor for the enzymatic synthesis of poly (ethylene glutarate).
General Description Colorless liquid with a mild pleasant odor. Density 9.2 lb /gal. Flash point 191°F. Boiling point 369°F. Combustible but requires some effort to ignite. Used in the manufacture of perfumes, printing ink, lacquers and resins.
Air & Water Reactions Water soluble.
Reactivity Profile Ethylene glycol diacetate reacts with aqueous acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction with caustic solutions. Flammable hydrogen is generated with alkali metals and hydrides.
Health Hazard Inhalation is not hazardous. Liquid causes mild irritation of eyes. Ingestion causes stupor or coma.
Fire Hazard Ethylene glycol diacetate is combustible.
Flammability and Explosibility Notclassified
Safety Profile Moderately toxic by intraperitoneal route. Mildly toxic by ingestion and skin contact. An eye irritant. Combustible when exposed to heat or flame; can react with oxidzing materials. To fight fire, use alcohol foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes.
Purification Methods Dry the di-ester with CaCl2, filter (excluding moisture) and fractionally distil it under reduced pressure. [Beilstein 2 IV 1541.]

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